Metal stabilized cyanoisocyanide; X-ray structure of [Cr(CO)5CNCN]

Abstract
[Cr(CO)5CNCN]3 and [Cr(CO)5CNCN] are synthesized by action on NEt4[Cr(CN)(CO)5] of cyanuric chloride and cyanogen chloride, respectively; the molecular structure of pentacarbonyl (cyanoisocyanide)-chromium(0) is established by single crystal X-ray diffraction.

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