Catalytic conversions in water. Part 9. High activity of the Pd/dpppr-s/Brønsted acid system in the alternating copolymerization of ethene and carbon monoxide {dpppr-s = C3H6-1,3-[P(C6H4-m-SO3Na)2]2}
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 3,p. 401-402
- https://doi.org/10.1039/a707572c
Abstract
The formation of alternating copolymers of ethene and carbon monoxide proceeds rapidly in the aqueous phase in the presence of a water-soluble palladium catalyst and a Brønsted acid; activities of >4 kg of polymer per g palladium per hour were observed.Keywords
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