Far-infrared spectrum of di-tetramethyltetraselenafulvalene hexafluoroarsenate [(TMTSF]
- 15 December 1985
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 32 (12) , 8041-8045
- https://doi.org/10.1103/physrevb.32.8041
Abstract
New results are presented on the far-infrared properties of the quasi-one-dimensional compound di-tetramethyltetraselenafulvalene hexafluoroarsenate [(TMTSF ] below the spin-density-wave (SDW) transition temperature. The infrared conductivity is reduced at frequencies below 60 but we do not observe a well-developed energy gap. A 5--wide mode centered at zero frequency can be observed with a strength that is consistent with the freezing out of carriers below the SDW transition as observed by dc conductivity. There is no evidence of high metallic single-particle conductivity in our measurements above the transition temperature in the conducting state. A strong continuous absorption in the 50–500- region can be seen and we associate it with a Holstein absorption with a of 0.6, a value that is consistent with the temperature dependence of the dc conductivity.
Keywords
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