Far-infrared spectrum of di-tetramethyltetraselenafulvalene hexafluoroarsenate [(TMTSF)2AsF6]

Abstract
New results are presented on the far-infrared properties of the quasi-one-dimensional compound di-tetramethyltetraselenafulvalene hexafluoroarsenate [(TMTSF)2 AsF6] below the spin-density-wave (SDW) transition temperature. The infrared conductivity is reduced at frequencies below 60 cm1 but we do not observe a well-developed energy gap. A 5-cm1-wide mode centered at zero frequency can be observed with a strength that is consistent with the freezing out of carriers below the SDW transition as observed by dc conductivity. There is no evidence of high metallic single-particle conductivity in our measurements above the transition temperature in the conducting state. A strong continuous absorption in the 50500-cm1 region can be seen and we associate it with a Holstein absorption with a λtr of 0.6, a value that is consistent with the temperature dependence of the dc conductivity.