Zur Kenntnis der sogenannten «Alkalicarbonyle» III. Die «Alkalicarbonyle» als Substangemische einer metalloganischen Verbindung und Metallacetylendiolaten
- 1 January 1963
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 46 (6) , 2111-2120
- https://doi.org/10.1002/hlca.19630460629
Abstract
The pyrophoric products obtained from the alkalimetals lithium, sodium, potassium, rubidium, and cesium with carbon monoxide in liquid ammonia are shown to be mixtures of the metal acetylene diolates, MOC COM, with an organometallic compounds, the possible structures of which are discussed.Keywords
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