Preparation and properties of trithiocarbonate SS-dioxides

Abstract
Dithiochloroformates react with metal sulphinates to give trithiocarbonate SS-dioxides (I), and phenyl dithiochloroformate and sodium methanesulphinate give phenyl (phenylthio)(methylsulphonyl)methyl disulphide (II); towards nucleophiles, the dioxides (I) behave as thioacylating agents.

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