Horseradish peroxidase-catalysed oxidation of aromatic tertiary amines with hydrogen peroxide
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 5,p. 456-460
- https://doi.org/10.1039/p19780000456
Abstract
The horseradish peroxidase-catalysed oxidation of aromatic tertiary amines with hydrogen peroxide leads to a secondary amine and an aldehyde. With alkylmethylanilines demethylation is preferred to dealkylation. Evidence is given for the coexistence of the usual peroxidation reaction and a free radical chain reaction which depends upon oxygen concentration.This publication has 5 references indexed in Scilit:
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- THE ENZYME-SUBSTRATE COMPOUNDS OF HORSERADISH PEROXIDASE AND PEROXIDES .2. KINETICS OF FORMATION AND DECOMPOSITION OF THE PRIMARY AND SECONDARY COMPLEXES1949