Reaction of nitric oxide with cobalt(II) ammine complexes and other reducing agents
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 943-946
- https://doi.org/10.1039/j19670000943
Abstract
Nitric oxide reacts with the “cobalt pentammine nitrosyl” ion, [CoIII(NH3)5(NO–)]2+, to give an intermediate, [Co(NH3)5(N2O2 –)]2+, which may react further with nitric oxide to give the hydroxopentamminecobalt(III) ion, nitrite, and nitrous oxide, or with excess of cobalt(II) to give decammine-µ-hyponitrodicobalt(III) salts. Chemical and spectroscopic evidence indicate a cis or skew configuration for the hyponitrite ligand. The reactions of nitric oxide with reducing agents are reviewed.Keywords
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