Notes. Crystal structure and electrical conduction properties of Rb[Pt{S2C2(CN)2}2]·2H2O. The precursor of a one-dimensional metal
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 8,p. 1759-1762
- https://doi.org/10.1039/dt9840001759
Abstract
The preparation, crystal structure, and electrical conduction properties of Rb[Pt{S2C2(CN)2}2]·2H2O are described. The planar anions are arranged in a dimeric eclipsed configuration to form a columnar stacked structure. The room-temperature conductivity in the platinum atom chain direction is 2.5 ×10–5Ω–1 cm–1 and the compound behaves as a semiconductor.Keywords
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