Facile α-H elimination in cationic zirconium alkyl complexes: Formation of μ-CH2 complexes as a possible deactivation pathway in polymerization catalysis
- 27 December 1994
- journal article
- research article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 484 (1-2) , c10-c12
- https://doi.org/10.1016/0022-328x(94)87213-9
Abstract
No abstract availableKeywords
This publication has 12 references indexed in Scilit:
- The first stable zirconium alkylidene complex formed via .alpha.-hydrogen abstraction: synthesis and x-ray crystal structure of [.eta.5-C5H3-1,3-(SiMe2CH2PPri2)2]Zr:CHPh(Cl)Journal of the American Chemical Society, 1993
- Base-free cationic zirconium benzyl complexes as highly active polymerization catalystsOrganometallics, 1993
- Surface-bound metal hydrocarbyls. Organometallic connections between heterogeneous and homogeneous catalysisAccounts of Chemical Research, 1992
- Reversible and irreversible deactivation of propene polymerization using homogeneous Cp2ZrCl2/methylaluminoxane Ziegler—Natta catalystsJournal of Organometallic Chemistry, 1991
- Chemistry of Cationic Dicyclopentadienyl Group 4 Metal-Alky I ComplexesPublished by Elsevier ,1991
- Darstellung, Struktur und Olefinpolymerisationsaktivität basenfreier kationischer 14‐Elektronen‐Alkyltitan‐ und ‐zirconiumkomplexeAngewandte Chemie, 1990
- Base‐Free Cationic 14‐Electron Titanium and Zirconium Alkyls: In situ Generation, Solution Structures, and Olefin Polymerization ActivityAngewandte Chemie International Edition in English, 1990
- Dinuclear Fulvalene Complexes of Tri‐ and Tetravalent ZirconiumAngewandte Chemie International Edition in English, 1987
- Zweikernige Fulvalen-Komplexe von drei- und vierwertigem ZirconiumAngewandte Chemie, 1987
- Synthesis of carbene complexes of Group IV metals from alkylidene-bridged heterobimetallic precursorsJournal of the American Chemical Society, 1983