Proton magnetic resonance investigation of the system zinc perchlorate–methanol: evidence for the association of zinc and perchlorate ions
- 15 April 1969
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 47 (8) , 1417-1421
- https://doi.org/10.1139/v69-231
Abstract
The proton magnetic resonance spectrum of the system zinc perchlorate–methanol is reported for a range of sample concentrations and temperatures. The results are interpreted in terms of association between the zinc and perchlorate ions, and the various features of the spectrum discussed in terms of this interaction. From the temperature-dependence of line-widths, Ea = 14 ± 2 kcal mole−1 and log10A = 16 ± 3 are estimated for the molecular exchange of methanol from the solvation shell of zinc into the bulk solvent.Keywords
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