Crystal structure of arsenic trichloride–trimethylamine, AsCl3,NMe3
- 1 January 1971
- journal article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 836-838
- https://doi.org/10.1039/j19710000836
Abstract
The title compound has been examined by single-crystal X-ray diffraction and crystallises in the space group P21/c with Z= 4 in a unit cell of dimensions a= 6·14, b= 10·33, c= 14·85 Å, and β= 107·0°. The structure consists of discrete AsCl3,NMe3 molecules which may be considered to be based on trigonal bipyramidal arsenic co-ordination and the photographically estimated three-dimensional data were refined to R 0·083.Keywords
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