Molybdenum-Catalyzed Asymmetric Allylic Alkylations
- 20 December 2003
- journal article
- Published by American Chemical Society (ACS) in Accounts of Chemical Research
- Vol. 37 (3) , 159-167
- https://doi.org/10.1021/ar030239v
Abstract
The highly regio- and enantioselective molybdenum-catalyzed allylic alkylation reaction has become a powerful synthetic tool during the past few years. This Account describes the achievements gained so far in the area, with special attention directed to the different chiral ligands that have been used for inducing chirality in the products, the range of allylic substrates and nucleophiles employed, mechanistic studies, and applications of the reaction in asymmetric syntheses.Keywords
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