Replacement of hydrido-ligands in [Ru3(µ-H)3(µ-H)3(µ3-COMe)(CO)9] and [Ru4(µ-H)4(CO)12] by triphenylphosphinegold groups: X-ray crystal structures of [AuRu3(µ-H)2(µ-COMe)(CO)9(PPh3)], [Au3Ru3(µ-COMe)(CO)9(PPh3)3], and [Au3Ru4(µ-H)(CO)12(PPh3)3]
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 773-775
- https://doi.org/10.1039/c39820000773
Abstract
The compounds [Ru3(µ-H)3-COMe)(CO)9 and [Ru4(µ-H)4(CO)12] react with [AuMe(PPh3)] to give gold–ruthenium cluster compounds, and the structures of [AuRu3(µ-H)2(µ3-COMe)(CO)9(PPh3)], [Au3Ru3(µ3-COMe)(CO)9(PPh3)3], and [Au3Ru4(µ-H)(CO)12(PPh3)3] have been established by single-cryst X-ray diffraction studies.Keywords
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