Dielectric measurements at radio frequencies in the presence of a strong static field
- 1 March 1975
- journal article
- research article
- Published by AIP Publishing in Review of Scientific Instruments
- Vol. 46 (3) , 306-311
- https://doi.org/10.1063/1.1134190
Abstract
A differential dielectric bridge is described for the measurement of small changes in the real and imaginary part of the dielectric permittivity effected by the application of a strong static field to a liquid. The apparatus is based on the resonant bridge principle and operates in the rf range (0.7−120 MHz). A dc field up to 250 kV/cm can be superimposed on the rf field. Chemical increments in the dielectric loss factor characteristic for chemical relaxation experiments of less than 1×10−7 are detectable. The apparatus can also be used as a conventional dielectric bridge whereby changes in the real part of 5×10−5 and in the imaginary part of the permittivity as low as 1×10−4 are measurable. The technique of the measurements is discussed and illustrative examples are provided.Keywords
This publication has 5 references indexed in Scilit:
- Chemical Relaxation as a Mechanistic Probe of Hydrogen Bonding. Thermodynamics and Kinetics of Lactam Isoassociation in Nonpolar SolventsThe Journal of Physical Chemistry, 1974
- A Thermodynamic and Kinetic Study on the Stability of the Conformational States of N‐Acetyl‐proline‐methylamide by IR. spectroscopy and chemical relaxationHelvetica Chimica Acta, 1974
- A Chemical Relaxation Study of Base Pairing through Self‐Association of Uracil and its Hetero‐Association with AdenineBerichte der Bunsengesellschaft für physikalische Chemie, 1973
- Die „unmeßbar”︁ schnellen Reaktionen (Nobel‐Vortrag)Angewandte Chemie, 1968
- Dielectric dispersion and chemical relaxationJournal of the American Chemical Society, 1968