Novel synthesis of platinum(II) alkenyl compounds via organoboration of platinum(II) acetylides
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 309-310
- https://doi.org/10.1039/c39830000309
Abstract
High-yield syntheses of two new types of platinum (II) alkenyl compounds are described: (i) organoboration of trans-[Pt(CC–H)2(PEt3)2] with R1 3B (R1= Me, Et, or Pri) leads to (E,E)-trans-[Pt(CHCR1BR1 2)2-(PEt3)2] and (ii) organoboration of trans-[Pt(CC–Me)2(PEt3)2] with R1 3B (R1= Me or Et) leads to (E)-trans-[Pt(CC–Me)(CMeCR1BR1 2)(PEt3)2].Keywords
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