Synthesis of cyclic allylic sulphides (ring sizes 5–15)via phenylthio participation
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 2,p. 303-311
- https://doi.org/10.1039/p19890000303
Abstract
Dehydration of β-phenylthio alcohols occurs with PhS participation unless stereochemistry prevents it. Without PhS participation, mixtures of allylic and vinylic sulphides are formed, but with PhS participation routes to three families of cyclic allylic sulphides (9), (13), and (14)(n= 5, 6, 7, 8, 10, 12, or 15) can be chosen. 2-exo-Methylenecycloalkanols were made from (14).Keywords
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