Synthesis of Silyl Enol and Silyl Dienol Ethers of 20-Oxosteroids: The Effect of β-Substituents
- 1 June 1997
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 26 (6) , 529-530
- https://doi.org/10.1246/cl.1997.529
Abstract
An efficient method to obtain regioselectively the title compounds is described. Experimental studies concerning the effect of β-substituents on the generation of β-substituted silyl enol ethers made feasible for the first time the isolation and identification of the products resulting from the unstable thermodynamic silyl enol ether.Keywords
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