An unusual anionic rearrangement in the (CH)10 series
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 599-600
- https://doi.org/10.1039/c39730000599
Abstract
Reaction of an excess of methyl-lithium with the tosylhydrazone of tricyclo[5,3,0,02,10]deca-3,5-dien-9-one affords tetracyclo[4,4,0,02,10,05,9]deca-3,7-diene, whereas reaction with 2 equiv. of methyl-lithium gives tricyclo[5,3,0,04,10]deca-2,5,8-triene.Keywords
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