Application of a rescaled mean spherical approximation to strongly interacting ionic micellar solutions
- 1 December 1985
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 32 (6) , 3807-3810
- https://doi.org/10.1103/physreva.32.3807
Abstract
We analyze a set of small-angle neutron scattering (SANS) data of micellar solutions using a re- scaled mean spherical approximation (MSA). The rescaling is shown to overcome the inaccuracy of MSA for the cases of dilute and strongly coupled solutions. The theory is in excellent agreement with SANS data for dilute as well as concentrated solutions. The counter-ion size effect is explicitly taken into account and the extracted renormalized micellar charges are reasonable but smaller, compared to that from the rescaled one-component macro-ion approximation.Keywords
This publication has 18 references indexed in Scilit:
- Structural properties of solutions of spherical micelles: Effect of finite size of small ionsThe Journal of Chemical Physics, 1985
- Size effects and polydispersity in ionic micellar solutions within the mean spherical approximationThe Journal of Physical Chemistry, 1985
- Ion binding and dressed micellesThe Journal of Physical Chemistry, 1984
- Determination of interparticle structure factors in ionic micellar solutions by small angle neutron scatteringThe Journal of Physical Chemistry, 1983
- Structure of ionic micelles from small angle neutron scatteringThe Journal of Physical Chemistry, 1983
- The interaction of two spherical colloidal particles in electrolyte solution. An application of the hypernetted-chain approximationThe Journal of Chemical Physics, 1980
- Application of the HNC approximation to systems of highly charged hard spheres (micelles)Chemical Physics Letters, 1977
- Mean spherical model approximation for the primitive model of sodium chlorideChemical Physics Letters, 1976
- Mean spherical model for asymmetric electrolytesMolecular Physics, 1975
- Ornstein–Zernike Relation and Percus–Yevick Approximation for Fluid MixturesThe Journal of Chemical Physics, 1970