An investigation of some iron halide complexes by Mössbauer spectroscopy
- 15 April 1969
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 47 (8) , 1351-1354
- https://doi.org/10.1139/v69-221
Abstract
The products of the reaction between iron carbonyls and various ligands have been examined by Mössbauer spectroscopy. With triphenylphosphine and triphenylarsine, complexes of Fe(III) in a tetrahedral configuration are produced. In all other cases the complexes contain Fe(II), and it is suggested that these are not monomeric, but are chlorine bridged complexes.Keywords
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