Molecular g Values, Magnetic Susceptibility Anisotropies, Molecular Quadrupole Moments, Diamagnetic and Paramagnetic Susceptibilities, and the Second Moment of the Electronic Charge Distribution in CHFO, CH2CHF, CF2CHF, CH3CH2F, and CH3CHF2
- 15 April 1971
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 54 (8) , 3450-3463
- https://doi.org/10.1063/1.1675364
Abstract
The high‐field rotational Zeeman effect has been observed in formyl fluoride (CHFO), vinyl fluoride (CH2CHF), trifluoroethylene (CF2CHF), ethyl fluoride (CH3CH2F), and 1, 1‐difluoroethane (CH3CHF2). The signs and magnitudes of the magnetic susceptibility anisotropies and the magnitudes of the molecular values were obtained and are listed. Although only the relative signs of the values could be obtained by experiment, the signs were determined through analysis of molecular quadrupole moments and the second moments of the electronic charge distribution. The molecular quadrupole moments are also given. Using the magnetic susceptibility anisotropies, values, the known structures, and the bulk susceptibilities, the diagonal elements of the paramagnetic, diamagnetic, and total susceptibility tensors were calculated along with the second moments of the electronic charge distribution.
Keywords
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