Möossbauer Study of FeMo2S4

Abstract
Mössbauer spectra of Fe 57 were taken at 79∼300 K for naonoclinic FeMo 2 S 4 with a layered structure. The divalent state of Fe was confirmed and the antiferromagnetic Néel temperature was determined as 101.5±0.5 K. The Fe 2+ spins were shown to lie nearly perpendicular to the a b plane of the monoclinic cell below the Néel point. The paramagnetic spectra taken near the Néel point contained additional unresolved lines, which was considered as a trace of the short range magnetic order due to the two dimensional nature of the magnetic order.

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