New cyclopentadienylcarbonyl derivatives of molybdenum
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1606-1607
- https://doi.org/10.1039/j19660001606
Abstract
Reaction of an excess of the halogen with the compound [C5H5Mo(CO)3]2 yields the derivatives C5H5Mo(CO)2X3(X = Cl, Br, or I), which are diamagnetic and non-electrolytes. Reaction of the tribromides with pyridine and 2,2-bipyridyl results in complete expulsion of carbon monoxide, to produce the impure compounds C5H5Mopy2Br3 and C5H5Mo bipyBr3, respectively.Keywords
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