Decamethylvanadocene forming a disulphur complex from elemental sulphur and desulphurization reactions
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 184-186
- https://doi.org/10.1039/c39830000184
Abstract
Bis(pentamethylcyclopentadienyl)vanadium(II) bonds to a disulphur ligand in reactions with elemental sulphur, COS, and [(salophen)Co–S2–Co(salophen)(tetrahydrofuran)2Na]+[salophen =N,N′-o-phenyl-enebis(salicylideneaminato)dianion] to form [(η5-C5Me5)2V(η2-S2)] which contains the persulphido-ligand [S–S, 2.028(4)Å].Keywords
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