C,N,N-Cyclometallated palladium(II) complexes: a step forward to luminescent metallomesogens
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 21,p. 2463-2464
- https://doi.org/10.1039/cc9960002463
Abstract
Cyclopalladation of 4′-functionalized 6′-phenyl-2,2′-bipyridine ligands (HLn, n= 1–3) leads to [PdLnCl] species as demonstrated by the crystal structure of [PdL1Cl]; thermotropic nematic mesomorphism is observed for HL3 and [PdL3Cl]; the latter is also photoluminescent at 77 K.Keywords
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