Synthesis and reactions of η3-5-oxocyclohexenyl(dicarbonyl)(η5-cyclopentadienyl)molybdenum
- 1 January 1989
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 389-391
- https://doi.org/10.1039/c39890000389
Abstract
Deprotonation of cyclohexadiene(dicarbonyl)(η5-cyclopentadienyl)molybdenum hexafluorophosphate (1) gives the η3-cyclohexadienyl complex (2) which is converted to the 5-oxocyclohexenyl complex (4) by hydroboration followed by Swern oxidation; generation of the enolate of (4) and its reactions with electrophiles are reported.Keywords
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