Abstract
The complete series of substituted halocarbonyl anions [Mo(CO)3RPh3X3]- (where R is P, Sb, As; X is Cl, Br) have been characterized as their tetraethyl-ammonium salts. Each substituted anion has been prepared by two distinct methods and all of the compounds can exist as two isomers. Except for the α-isomer of [Mo(CO)3PPh3Br3]- these complexes are reported for the first time.

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