Four coordinate bis(imido) alkene complexes of molybdenum(IV): relatives of the zirconocene family
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1666-1668
- https://doi.org/10.1039/c39920001666
Abstract
The unusual four coordinate bis(imido) alkene complexes [Mo(NBut)2(CH2 CHR)(PMe3)](R = H, Me) have been synthesised via treatment of [Mo(NBut)2Cl2(dme)](dme = dimethoxyethane) with two equivalents of RCH2CH2MgCl (R = H, Me) in the presence of PMe3; the molecular structure of the propene derivative is reported.Keywords
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