Notizen: Thiol Ester Aminolysis in Acetonitrile
Open Access
- 1 February 1975
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 30 (1-2) , 138
- https://doi.org/10.1515/znb-1975-1-236
Abstract
The kinetics of the reactions of p-nitrophenyl thiolacetate with several amines in acetonitrile was studied. Hydrazine exhibits considerably greater nucleophilicity than expected from its pKa value. Common mechanism is suggested for the aminolysis of the thiol ester and its oxygen analogue.Keywords
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