Unusual intermolecular ligand exchange process in octakis(trimethylphosphite)dirhodium(0), Rh2[P(OMe)3]8
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 147
- https://doi.org/10.1039/c39740000147
Abstract
The new complex Rh2[P(OMe)3]8 which has a bicapped trigonal antiprismatic structure at room temperature undergoes a specific equatorial intermolecular ligand exchange at higher temperatures rather than any intramolecular ligand exchange between equatorial and axial sites.Keywords
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