Fluoroacrylate-Bound Fluorous-Phase Soluble Hydrogenation Catalysts
- 20 January 2000
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 2 (3) , 393-395
- https://doi.org/10.1021/ol991352h
Abstract
[reaction: see text] Fluoroacrylate polymer-bound hydrogenation catalysts are described. N-Acryloxysuccinimide-containing fluoroacrylate polymers were converted into phosphine ligands and subsequently into analogues of Wilkinson's catalyst by amidation of N-acryloxysuccinimide active ester residues and Rh exchange. The resulting catalysts have excellent activity and can be reused following fluorous biphasic liquid/liquid separation and extraction.Keywords
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