Enhanced reactivity of nucleophiles: the “α-effect” in reactions of benzyl bromide
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 20,p. 1378-1379
- https://doi.org/10.1039/c29700001378
Abstract
Benzyl bromide reacts rapidly with amidoximes in the neutral form by intramolecular base catalysis, and N-methylhydroxmic acids also show enhanced reactivity, attributed in this case to lone-pair repulsion.Keywords
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