THE RELATIVE ACCEPTOR POWER OF BORON TRIHALIDES AND BORANE TOWARD TRIMETHYLAMINE
- 1 November 1963
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 41 (11) , 2898-2902
- https://doi.org/10.1139/v63-424
Abstract
Gas phase displacement reactions of boron trihalides from their trimethylamine adducts show that the order of acceptor power is: BBr3 > BCl3 > BF3 > 1/2(B2H6). This order agrees with recent theoretical calculations and dipole moment, calorimetric, and infrared measurements on boron trihalide complexes with other reference bases.Keywords
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