Studies of the Metal Complexes of Cyclohexane Derivatives. V. Copper(II) and Nickel(II) Complexes of cis-1,3-Cyclohexanediamine
- 1 January 1979
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 52 (1) , 57-60
- https://doi.org/10.1246/bcsj.52.57
Abstract
A series of 1,3-chxn(cis-1,3-cyclohexanediamine) copper(II) and nickel(II) complexes have been prepared and studied using spectroscopic and magnetic techniques. The violet and red copper(II) complexes of 1,3-chxn were found to consist of monomeric distorted octahedra and slightly distorted square planers, respectively. The nickel(II) complexes have a square planar structure. The conformational change of the ligand from diequatorial to diaxial on coordination has been confirmed by infrared analysis.Keywords
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