Homogeneous catalytic activation of O–H and N–H bonds in organic molecules by ruthenium, osmium, rhodium, and iridium complexes
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 290-291
- https://doi.org/10.1039/c39720000290
Abstract
H–D isotopic exchange between D2 and CH3COOH, CH3OH, C2H5OH or morpholine is observed in the presence of some RuII, OsII, RhI or IrI complexes at ambient conditions; analogous compounds of Pt0,II, Pd0,II, NiII, CoII and FeII are inactive.Keywords
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