Heteroatomic Modulation of Oxyanionic Cope Rearrangement Rates. Consequences on Competing Nucleophilic Cleavage of an Oxetane Ring in Precursors to Paclitaxel
- 25 August 1998
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 63 (19) , 6432-6433
- https://doi.org/10.1021/jo981059f
Abstract
No abstract availableThis publication has 16 references indexed in Scilit:
- Enantiospecific Total Synthesis of Natural (+)-Taxusin. 2. Functionalization of the A-Ring and Arrival at the TargetJournal of the American Chemical Society, 1998
- Enantiospecific Total Synthesis of Natural (+)-Taxusin. 1. Retrosynthesis, Advancement to Diastereomeric trans-Δ9,10-Tricyclic Olefinic Intermediates, and the Stereocontrol Attainable Because of Intrinsic Rotational Barriers ThereinJournal of the American Chemical Society, 1998
- Bicyclic Systems Related to Taxol. A Direct Means for Implementing C-2 Oxygenation and Demonstration of the Feasibility of α-Ketol Equilibration in a Fully Oxygenated B-Ring SettingThe Journal of Organic Chemistry, 1998
- An Abbreviated, Highly Stereocontrolled Route to Precursors of Taxol. Elaboration of a Fully Functionalized C Ring by Means of Intramolecular Aldol CyclizationThe Journal of Organic Chemistry, 1995
- Evaluation of D-Ribose as an Enantiopure Building Block for Construction of the C-Ring of Taxol and Its CongenersThe Journal of Organic Chemistry, 1995
- Evaluation of 2-Bromocyclohexenone Acetals as Vehicles for the Introduction of C-7 Oxygen Preliminary to the Synthesis of Taxane DiterpenesThe Journal of Organic Chemistry, 1995
- Stereocontrolled Oxygenation of Camphor Derivatives as a Prelude to the Complete .beta.-Ring Functionalization of Potential Precursors to Taxol and Structural Analogs ThereofThe Journal of Organic Chemistry, 1995
- Stereocontrolled Construction of Complex Cyclic Ketones via Oxy‐Cope RearrangementAngewandte Chemie International Edition in English, 1990
- [3.3] Sigmatropy within 1-vinyl-2-alkenyl-7,7-dimethyl-exo-norbornan-2-ols. The first atropselective oxyanionic Cope rearrangementJournal of the American Chemical Society, 1990
- Ene‐sulfides as Reaction Partners of Organometallic CompoundsHelvetica Chimica Acta, 1976