X-ray structure analysis of trans-1,4-polybutadiene
- 1 June 1968
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science, Part B
- Vol. 2 (2) , 163-177
- https://doi.org/10.1080/00222346808212447
Abstract
The crystal structure of trans-1,4-polybutadiene has been reported by Natta et al. to be pseudo-hexagonal below its solid-phase transition temperature. In the present X-ray structure analysis, it is revealed that the crystal belongs to the monoclinic system with the space group P21/a. The unit cell, with the lattice constants a = 8.63 Å, b = 9.11 Å, c = 4.83 Å, and β = 114°, includes four molecular segments.Keywords
This publication has 2 references indexed in Scilit:
- Macromolecular ChemistryScience, 1965
- General considerations on the structure of crystalline polyhydrocarbonsIl Nuovo Cimento (1869-1876), 1960