Acetyl Migration in Partially Acetylated D-Glucopyrano-Sides and Acylamidohexopyranosides
- 1 January 1983
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 2 (3) , 279-292
- https://doi.org/10.1080/07328308308057874
Abstract
O-4-O-6 Acetyl migrations in partially O-acetylated 2- and 3-acylamidodeoxyhexopyranosides, including derivatives of kanamycin A, were found to be particularly suited to allow the regiospecific accessibility of their respective C-4 OH groups. Partially O-acetylated d-glucopyranosides, compared to the substrates above, showed slightly different aptitudes of migration. However, all O-4-O-6 migrations investigated proved to be irreversible under the conditions applied.This publication has 19 references indexed in Scilit:
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