A novel 4-aminobenzyl ester-based carboxy-protecting group for synthesis of atypical peptides by Fmoc-But solid-phase chemistry
- 1 January 1995
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 2209-2210
- https://doi.org/10.1039/c39950002209
Abstract
4{N-[1-(4, 4-Dimethyl-2,6-dioxocyclohexylidene)-3-methylbutyl]amino}benzyl ester (ODmab) is a new carboxy-protecting group that is based on the safety-catch principle and can be used orthogonally with Fmoc-Butpeptide chemistry, but is completely removable with 2%v/v hydrazine·H2O-DMF at room temperature within minutes.Keywords
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