Suzuki−Miyaura Cross-Coupling of Benzylic Carbonates with Arylboronic Acids
- 4 February 2005
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 7 (5) , 945-947
- https://doi.org/10.1021/ol050078q
Abstract
The cross-coupling of benzylic carbonates with arylboronic acids gave the corresponding diarylmethanes in high yields by use of the palladium catalyst generated in situ from [Pd(eta(3)-C(3)H(5))Cl](2) and 1,5-bis(diphenylphosphino)pentane (DPPPent). The Suzuki-Miyaura reaction using DPPPent-palladium catalyst is applicable to syntheses of a broad range of functionalized diarylmethanes. [reaction: see text]Keywords
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