Greatly attenuated reactivity of nitrile-derived carbon-centered radicals toward oxygen
- 20 June 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1576-1577
- https://doi.org/10.1039/b203158b
Abstract
Several cyanoalkyl radicals are reported to be unreactive toward oxygen; spin delocalization on nitrogen is proposed to be the most important factor to explain this unusual behaviour.Keywords
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