Enzymatic regioselective alkoxycarbonylation of hexoses and pentoses with carbonate oxime esters
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 5,p. 589-592
- https://doi.org/10.1039/p19930000589
Abstract
Hexoses and pentoses have been alkoxycarbonylated with different preparations of Candida antarctica lipase, using acetone O-(alkoxycarbonyl)oximes. A wide variety of alkoxycarbonyl groups are introduced in an easy manner at the primary hydroxy group of several pentoses and hexoses. Of especial importance are the introduction of allyloxy- and benzyloxy-carbonyl groups.Keywords
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