Eigenvalues of any parameter in the Schrodinger radial equation
- 14 December 1980
- journal article
- Published by IOP Publishing in Journal of Physics B: Atomic and Molecular Physics
- Vol. 13 (23) , 4521-4528
- https://doi.org/10.1088/0022-3700/13/23/010
Abstract
The behaviour of the solution of the Schrodinger radial equation has been studied experimentally. From this study, a very simple and short computing program has been devised for computing the eigenvalues and eigenfunctions of the energy, and for computing the eigenvalues and eigenfunctions of any parameter that may exist in the potential expression. The number of iterations for reaching convergence to a precision of 9 significant figures is 6 (i.e. less than the previous program by a factor of 1/5). The total computing time is reduced by a factor of 1/20. This program is so short (about 20 statements) that presenting it, is easier than describing it. An example is given with sample data and test output. Linear extrapolation is used to find the trial values of each eigenvalue at each iteration. This method is found to be simpler, faster, and more accurate than other methods. By the use of this program it is possible to solve the 'inverse eigenvalue problem'.Keywords
This publication has 13 references indexed in Scilit:
- Analytic potential with adjusted parameters for diatomic moleculesPhysical Review A, 1975
- Internuclear potential for the B state of N+2Physics Letters A, 1975
- On the numerical solution of schroedinger's radial equationJournal of Computational Physics, 1974
- Numerical potential of diatomic molecules: quantum methodJournal of Physics B: Atomic and Molecular Physics, 1974
- Fast determination of resonance states in atomic collisionsChemical Physics Letters, 1970
- Bound vibrational states for weakly attractive potentialsMolecular Physics, 1969
- Practical points concerning the solution of the Schrödinger equationJournal of Computational Physics, 1967
- Testing of Diatomic Potential-Energy Functions by Numerical MethodsThe Journal of Chemical Physics, 1963
- The Vibrational Levels of an Anharmonic OscillatorPhysical Review B, 1946
- Diatomic Molecules According to the Wave Mechanics. II. Vibrational LevelsPhysical Review B, 1929