Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5- dienes: a new tin-free homolytic route to β- and γ-lactams
- 9 November 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 23,p. 2327-2328
- https://doi.org/10.1039/b007454n
Abstract
Radical induced homolyses of 1-carbamoyl-1-methylcyclohexa-2,5-dienes took place cleanly to yield aminoacyl radicals, with no competition from the alternative dissociation to methyl radicals: β- and γ-lactams were obtained from ring closures of suitably unsaturated model compounds.Keywords
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