Novel routes to furan-3(2H)-ones. New syntheses of bullatenone and geiparvarin
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 3,p. 535-539
- https://doi.org/10.1039/p19840000535
Abstract
New convenient versatile routes to the furan-3(2H)-one nucleus are described as exemplified by the synthesis of the two natural products bullatenone (1) and geiparvarin (2). The key step involves the hydration and cyclisation of the corresponding readily accessible acetylenic ketones which are best made by a Pd(II)–Cu(I)-catalysed coupling process.This publication has 3 references indexed in Scilit:
- Silyl nitronates in organic synthesis. Synthesis of 3(2H)-furanonesTetrahedron, 1983
- Synthesis and configurational assignment of geiparvarin: a novel antitumor agentThe Journal of Organic Chemistry, 1981
- The coumarins of Geijera parviflora LindlAustralian Journal of Chemistry, 1967