The effect of molecular structure on molecular dynamics and ordering in a chiral smectic liquid crystal

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Abstract
The effect of a branched alkyl chain on molecular dynamics and ordering in a chiral smectic liquid crystal has been investigated by means of DSC, optical microscopy, powder X-ray diffraction, and solid state C-13 NMR. The introduction of a second branched alkyl chain into a S*C molecule increases the molecular tilt angle, the value of the spontaneous polarization in the S*C phase, and the SA–S*C transition enthalpy. The long-range order observed by X-ray measurements and the molecular motion detected by C-13 spin relaxation are not influenced by the branched group. On the other hand, marked NMR line broadenings for the core carbons occur in the oriented S*C phase. The results obtained suggest that the branched group affects the dynamics and ordering of the molecular core in the S*C phase through the interlayer interaction.