The ν3 fundamental of silicon tetrafluoride. Spectroscopy with laser sidebands

Abstract
The ν3 fundamental of 28SiF4 has been investigated with laser sidebands and infrared radio-frequency double resonance. From 165 infrared and 206 pure rotational transitions, 10 ground state and 22 excited state constants have been determined. The calculation was performed with a Hamiltonian developed up to sixth order.

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