Kinetic mechanism of threonyl-tRNA synthetase from human placenta

Abstract
Using purified enzyme and homologous tRNA, the order of substrate binding and product release for the human placental threonyl-tRNA synthetase was investigated by isotope exchange, initial velocity, dead-end inhibition and product inhibition studies. The kinetic patterns obtained from these studies are consistent with a unique Bi Uni Uni Bi ping-pong mechanism. The order of addition of the first 2 substrates ATP and threonine is random, while the release of products follows an obligatory sequence, with AMP as the last product to dissociate from the enzyme.

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