Solid-State Coordination Chemistry: The Self-Assembly of Microporous Organic-Inorganic Hybrid Frameworks Constructed from Tetrapyridylporphyrin and Bimetallic Oxide Chains or Oxide Clusters
- 2 November 1999
- journal article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (21) , 3165-3168
- https://doi.org/10.1002/(sici)1521-3773(19991102)38:21<3165::aid-anie3165>3.0.co;2-o
Abstract
The hydrothermal reactions of MoO(3), tetrapyridylporphyrin (tpypor), water, and the appropriate M(II) precursor yield the first examples of three-dimensional framework materials constructed from metal oxide and porphyrin subunits. The picture shows a section of [{Fe(tpypor)}(3)Fe(Mo(6)O(19))(2)] small middle dotx H(2)O with the [Fe(8)(tpypor)(6)](8+) building block of the cationic framework and the entrained {Mo(6)O(19)}(2-) cluster.Keywords
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