Mass spectra of aniline glucuronides

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Abstract
Mass spectra of TMS derivatives of aniline glucuronide and pentachloroaniline glucuronide are presented, and the fragmentation of these derivatives is compared with that of TMS aryl-O-glucuronides. Fragmentation yielding ions entirely from the glycone moiety was sufficiently similar to establish these N-glucuronides as TMS glucuronides in the same manner used for TMS-O-glucuronides; however, differences observed may be diagnostic for TMS N-glucuronides.

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